全文获取类型
收费全文 | 1411篇 |
免费 | 108篇 |
国内免费 | 344篇 |
专业分类
化学 | 686篇 |
晶体学 | 4篇 |
力学 | 592篇 |
综合类 | 43篇 |
数学 | 37篇 |
物理学 | 501篇 |
出版年
2024年 | 4篇 |
2023年 | 19篇 |
2022年 | 49篇 |
2021年 | 36篇 |
2020年 | 51篇 |
2019年 | 38篇 |
2018年 | 36篇 |
2017年 | 61篇 |
2016年 | 64篇 |
2015年 | 63篇 |
2014年 | 60篇 |
2013年 | 137篇 |
2012年 | 78篇 |
2011年 | 122篇 |
2010年 | 87篇 |
2009年 | 91篇 |
2008年 | 98篇 |
2007年 | 72篇 |
2006年 | 105篇 |
2005年 | 93篇 |
2004年 | 64篇 |
2003年 | 58篇 |
2002年 | 57篇 |
2001年 | 45篇 |
2000年 | 36篇 |
1999年 | 36篇 |
1998年 | 39篇 |
1997年 | 30篇 |
1996年 | 33篇 |
1995年 | 23篇 |
1994年 | 17篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1978年 | 1篇 |
排序方式: 共有1863条查询结果,搜索用时 15 毫秒
91.
The adsorption and corrosion inhibition behavior of synthesized Schiff base-based cationic gemini surfactant bis[p-(N,N,N-tetradecyldimethylammonium bromide)benzylidene]thiourea (14-S-14) on mild steel in 20% formic acid in the temperature range of 30°C to 60°C was evaluated using weight loss measurements, solvent analysis of iron ions and potentiodynamic polarization measurements. The synthesized inhibitor was characterized using Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and thin layer chromatography (TLC). The surface morphology of the corroded mild steel specimen was evaluated using scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDAX), and atomic force microscopy (AFM). Thermodynamic/kinetic parameters were calculated to elaborate the adsorption and corrosion inhibition mechanism of the inhibitor. The inhibition efficiency of the compound was found to vary with inhibitor concentration, immersion time, and temperature. The adsorption of the compound on the steel surface was found to obey Langmuir adsorption isotherm. 相似文献
92.
Mahendra Yadav Sushil Kumar Rajesh Ranjan Sinha Sumit Kumar 《Journal of Dispersion Science and Technology》2014,35(12):1751-1763
Imidazole derivatives, namely, 1-((1-(piperazinomethyl)-1H-benzoimidazol-2-yl)methyl)-2-phenylhydrazine (PBIP), and 1-((1-(morpholinomethyl)-1H-benzoimidazol-2-yl)methyl)-2-phenylhydrazine (MBIP) were synthesized and investigated as inhibitors for mild steel corrosion in 15% HCl solution using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques. It was found that the inhibition efficiency of both the inhibitors increases with increase in concentration of inhibitors and decreases with increase in temperature. The inhibitors, PBIP and MBIP, show corrosion inhibition efficiency of 92.6% and 91.4% at 300 ppm concentration, respectively, at 303 K. Polarization studies showed that both the studied inhibitors were of mixed type in nature. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were performed for surface study of uninhibited and inhibited mild steel samples. The semi-empirical AM1 method was employed for theoretical calculations. 相似文献
93.
The corrosion inhibition of mild steel in hydrochloric acid solution in the presence of three different molecular weights of polyvinyl alcohol (PVA) designated as PVA-I, PVA-II, and PVA-III corresponding to 14,000, 72,000, and 125,000 g mol?1, respectively, was investigated using electrochemical impedance spectroscopy, linear polarization resistance (LPR), and potentiodynamic polarization techniques at 25°C. It was found that PVA of different molecular weights inhibited the corrosion of mild steel in the acid environment. Inhibition efficiency (η%) increases with increase in concentration of the polymers. LPR measurements clearly show that inhibition efficiency increases with increasing molecular weight in the order PVA-III > PVA-II > PVA-I. Polarization curves indicate that PVA functions as a mixed inhibitor affecting both the anodic metal dissolution and cathodic hydrogen evolution partial reactions of the corrosion process. The experimental data obtained fitted well into Langmuir adsorption isotherm model. Physical adsorption mechanism is proposed from the thermodynamic (free energy of adsorption) parameters obtained. 相似文献
94.
95.
2-十一烷基-N-羧甲基-N-羟乙基咪唑啉在柠檬酸溶液中对碳钢的缓蚀作用 总被引:2,自引:1,他引:1
采用失重实验、极化曲线和交流阻抗等方法研究了缓蚀剂2-十一烷基-N-羧甲基-N-羟乙基咪唑啉在质量分数为2%柠檬酸溶液中对碳钢的缓蚀性能。 失重实验表明,该缓蚀剂在柠檬酸溶液中能够有效地抑制碳钢的腐蚀,当其质量分数为0.4%时,缓蚀效率达到86.4%。 极化曲线表明,该缓蚀剂为混合型缓蚀剂,Nyquist图中单一的容抗弧变化表明碳钢电极表面的腐蚀过程主要由电荷转移步骤控制。 该缓蚀剂的吸附行为符合Langmuir吸附等温式,吸附机理是介于物理吸附和化学吸附之间的一种吸附。 相似文献
96.
97.
应用腐蚀电位(Ecorr)、极化电阻(Rp)和砂浆保护层电阻率(ρc)研究了苯并三唑(BTA)对钢筋电极腐蚀电化学行为的影响. 通过电化学阻抗谱(EIS)、循环极化(CP)和循环伏安(CV)结果对比了BTA与NaNO2 (SN)对钢筋电极在未处理、预锈蚀和内掺氯盐3种状态下3.5% (w)氯盐浸泡360 d后的阻锈效率. 利用环境扫描电镜(ESEM)与能谱分析(EDS)解释了BTA对水泥基材料中钢筋的阻锈机理. 结果表明: 3种状态下BTA均能明显降低砂浆中钢筋的均匀腐蚀速率, 且其阻锈效率高于SN. 在未处理与预锈状态下, BTA抑制点蚀的能力稍弱于SN; 但在内掺氯盐的状态下, BTA表现出了较大的点蚀阻力. BTA除了能在钢筋表面形成复杂的保护膜, 从而有效抑制氯盐的破钝化作用. ESEM/EDS结果表明BTA还能与砂浆基体形成较多富钙C-S-H凝胶, 可能优化了钢筋/砂浆界面区的孔结构, 形成更致密的微观结构, 显著延缓了氯盐向钢筋表面的传输进程, 较好地保护了钢筋. 适量的BTA对砂浆360 d的基本力学性能无明显影响. 相似文献
98.
LI Dang-guo CHEN Da-rong WANG Jia-dao CHEN Hao-sheng State Key Laboratory of Tribology Tsinghua University Beijing P.R.China 《高等学校化学研究》2011,(4):697-702
The semi-conductive performances of hot growth film on 316L stainless steel were studied by means of electrochemical impedance spectroscopy(EIS) and Mott-Schottky analysis.The chemical compositions of the hot growth films were detected by X-ray photoelectron spectroscopy(XPS).The results show that the transfer resistance and film resistance increase with increasing temperature to 400℃,then they decrease sharply with further continuously increasing temperature.Formation time plays an important role in determ... 相似文献
99.
N80钢CO2腐蚀产物膜在水/砂两相流介质中的磨损性能 总被引:6,自引:1,他引:6
采用高温高压静态釜对N80油套钢在CO2中的腐蚀行为进行了模拟腐蚀试验;利用自制的磨损试验装置对比分析了腐蚀产物膜在水/砂两相介质中的磨损性能同成膜温度、CO2压力、流速及砂粒度之间的关系;用扫描电子显微镜分析了N80钢表面CO2腐蚀产物膜及其磨损表面形貌,用表面形貌仪测定了磨损试验前钢表面CO2腐蚀产物膜的粗糙度.结果表明:成膜温度和压力对钢表面腐蚀产物膜的表面粗糙度具有显著影响;N80钢表面CO2腐蚀产物膜磨损表面形貌沿深度方向存在差异,对应的抗磨性能亦有所不同;两相介质中的砂粒度越大或流体相对流速越大,则腐蚀膜的磨损越剧烈. 相似文献
100.